Switchable-Hydrophilicity Solvents for Product Isolation and Catalyst Recycling in Organocatalysis
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چکیده
منابع مشابه
Switchable-Hydrophilicity Solvents for Product Isolation and Catalyst Recycling in Organocatalysis.
Switchable-hydrophilicity solvents (SHSs) are solvents that can switch reversibly between a water-miscible state to a state that forms a biphasic mixture with water. In this case study, SHSs have been studied for easy product/catalyst separation as well as catalyst recycling. A series of tertiary amine SHSs have been identified for the extraction of the hydrophilic product from the postreaction...
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A switchable-hydrophilicity solvent (SHS) is a solvent that in one state forms a biphasic mixture with water but can be reversibly switched to another state that is miscible with water. We describe a mathematical model of the behaviour of CO2-triggered SHS that narrows the search field for these solvents in terms of their basicity and hydrophilicity. By its predictive power, the mathematical mo...
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ژورنال
عنوان ژورنال: ChemSusChem
سال: 2016
ISSN: 1864-5631
DOI: 10.1002/cssc.201501654